The Spray-On-Shoes formula is the first failed experimenment invented by Flint Lockwood, which resulted in becoming his shoes permantley with no way to (actually) get them off.
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The Spray-On Shoes were created for an untied shoes epidemic, but they failed because the user can't take of the shoes. The spray on shoes later helped Flint Lockwood destroy the corrupted FLSDMDFR. And even later the spray on shoes were used for roof sealent.